1. Identity statement | |
Reference Type | Journal Article |
Site | mtc-m21d.sid.inpe.br |
Holder Code | isadg {BR SPINPE} ibi 8JMKD3MGPCW/3DT298S |
Identifier | 8JMKD3MGP3W34T/49SMRME |
Repository | sid.inpe.br/mtc-m21d/2023/09.25.17.53 (restricted access) |
Last Update | 2023:09.25.17.53.42 (UTC) simone |
Metadata Repository | sid.inpe.br/mtc-m21d/2023/09.25.17.53.42 |
Metadata Last Update | 2024:01.02.17.16.47 (UTC) administrator |
DOI | 10.1016/j.diamond.2023.110367 |
ISSN | 0925-9635 |
Citation Key | SilvaQuiZanCorFat:2023:AmFlIn |
Title | Amperometric flow injection analysis of hydroquinone in dermatological creams using a porous diamond-like carbon electrode |
Year | 2023 |
Month | Nov. |
Access Date | 2024, May 28 |
Type of Work | journal article |
Secondary Type | PRE PI |
Number of Files | 1 |
Size | 1445 KiB |
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2. Context | |
Author | 1 Silva, Tiago Almeida 2 Quintão, Herlon Charlles Moura 3 Zanin, Hudson 4 Corat, Evaldo José 5 Fatibello-Filho, Orlando |
Resume Identifier | 1 2 3 4 8JMKD3MGP5W/3C9JH33 |
Group | 1 2 3 4 COPDT-CGIP-INPE-MCTI-GOV-BR |
Affiliation | 1 Universidade Federal de Viçosa (UFV) 2 Centro Federal de Educação Tecnológica de Minas Gerais (CEFET) 3 Universidade Estadual de Campinas (UNICAMP) 4 Instituto Nacional de Pesquisas Espaciais (INPE) 5 Universidade Federal de São Carlos (UFSCar) |
Author e-Mail Address | 1 tiago.a.silva@ufv.br 2 3 4 evaldo.corat@inpe.br |
Journal | Diamond and Related Materials |
Volume | 139 |
Pages | e110367 |
Secondary Mark | A1_ENGENHARIAS_IV A1_ENGENHARIAS_II A2_MATERIAIS A2_ENGENHARIAS_III B1_MEDICINA_I B2_QUÍMICA B2_CIÊNCIAS_BIOLÓGICAS_I B2_BIOTECNOLOGIA B2_ASTRONOMIA_/_FÍSICA |
History (UTC) | 2023-09-25 17:53:42 :: simone -> administrator :: 2023-09-25 17:53:46 :: administrator -> simone :: 2023 2023-09-25 17:55:59 :: simone -> administrator :: 2023 2024-01-02 17:16:47 :: administrator -> simone :: 2023 |
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3. Content and structure | |
Is the master or a copy? | is the master |
Content Stage | completed |
Transferable | 1 |
Content Type | External Contribution |
Version Type | publisher |
Keywords | Carbon nanotube forest Dermatologic samples Diamond-like carbon Flow injection analysis Hydroquinone |
Abstract | A porous diamond-like carbon film deposited on vertically aligned multi-walled carbon nanotubes (DLC:VAMWCNT) was evaluated as an electrode material in flow injection analysis (FIA) with amperometric detection. The redox behavior of hydroquinone (H2Q) was carried out as proof of concept. From cyclic voltammetry tests, H2Q gave a heterogeneous electron transfer rate constant (k0) of 4.9 × 10−3 cm s−1, which is comparable or better than those obtained with conventional electrodes. For the H2Q determination with the FIA-amperometry system, optimizations were performed regarding the supporting electrolyte, applied potential and FIA parameters (flow rate and sample injection volume). Under optimal conditions, the amperometric response of the DLC:VAMWCNT electrode was linear in the H2Q concentration range from 1.0 × 10−6 to 1.0 × 10−4 mol L−1, with a limit of detection (LOD) of 7.7 × 10−7 mol L−1. Interestingly, the DLC:VAMWCNT electrode displayed a very stable response under hydrodynamic conditions, with no memory effect while retaining accuracy towards the analysis of commercial H2Q-based dermatological creams. From these findings, DLC:VAMWCNT appears to be an outstanding candidate for flow injection analysis systems coupled to electrochemical detection. |
Area | FISMAT |
Arrangement | urlib.net > BDMCI > Fonds > Produção a partir de 2021 > CGIP > Amperometric flow injection... |
doc Directory Content | access |
source Directory Content | there are no files |
agreement Directory Content | |
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4. Conditions of access and use | |
Language | en |
Target File | 1-s2.0-S0925963523006921-main.pdf |
User Group | simone |
Reader Group | administrator simone |
Visibility | shown |
Archiving Policy | denypublisher denyfinaldraft24 |
Read Permission | deny from all and allow from 150.163 |
Update Permission | not transferred |
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5. Allied materials | |
Next Higher Units | 8JMKD3MGPCW/46KUES5 |
Citing Item List | sid.inpe.br/bibdigital/2022/04.03.23.11 6 sid.inpe.br/mtc-m21/2012/07.13.14.45.37 2 |
Dissemination | WEBSCI; PORTALCAPES; COMPENDEX; SCOPUS. |
Host Collection | urlib.net/www/2021/06.04.03.40 |
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6. Notes | |
Empty Fields | alternatejournal archivist callnumber copyholder copyright creatorhistory descriptionlevel e-mailaddress format isbn label lineage mark mirrorrepository nextedition notes number orcid parameterlist parentrepositories previousedition previouslowerunit progress project rightsholder schedulinginformation secondarydate secondarykey session shorttitle sponsor subject tertiarymark tertiarytype url |
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7. Description control | |
e-Mail (login) | simone |
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